INDUCED BREAKDOWN SPECTROSCOPY; EMISSION-SPECTROSCOPY; MOLECULAR-EMISSION; ABLATION; AIR; CARBON; ALO; TEMPERATURE; GENERATION; CHEMISTRY

Experimental investigations into the characteristics of laser-induced plasmas indicate that LIBS provides a relatively inexpensive and easily replicable laboratory technique to isolate and measure reactions germane to understanding aspects of high-explosive detonations under controlled conditions. Spectral signatures and derived physical parameters following laser ablation of aluminum, graphite and laser-sparked air are examined as they relate to those observed following detonation of high explosives and as they relate to shocked air. Laser-induced breakdown spectroscopy (LIBS) reliably correlates reactions involving atomic Al and aluminum monoxide (AlO) with respect to both emission spectra and temperatures, as compared to small-and large-scale high-explosive detonations. Atomic Al and AlO resulting from laser ablation and a cited small-scale study, decay within similar to 10(-5) s, roughly 100 times faster than the Al and AlO decay rates (similar to 10(-3) s) observed following the large-scale detonation of an Al-encased explosive. Temperatures and species produced in laser-sparked air are compared to those produced with laser ablated graphite in air. With graphite present, CN is dominant relative to N-2(+). In studies where the height of the ablating laser's focus was altered relative to the surface of the graphite substrate, CN concentration was found to decrease with laser focus below the graphite surface, indicating that laser intensity is a critical factor in the production of CN, via reactive nitrogen. (C) 2017 Author(s).